Super-Nernstian Tafel slopes: An origin in coupled homogeneous kinetics
نویسندگان
چکیده
منابع مشابه
Beyond the Butler-Volmer equation. Curved Tafel slopes from steady-state current-voltage curves.
We report the discovery and analysis of curved Tafel slopes from the electrochemical reduction of hexamminecobalt(III) under steady-state conditions. In order to confirm the existence of the curvature, random assemblies of carbon microelectrodes (RAM™ electrodes) were employed to obtain experimental data over more than three orders of magnitude, without significant double layer charging current...
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ژورنال
عنوان ژورنال: Journal of Electroanalytical Chemistry
سال: 2020
ISSN: 1572-6657
DOI: 10.1016/j.jelechem.2020.114185